Methoxyethyl carbamate → HCID 14365707, compound

Participants

Reaction Conditions

Reaction Steps

6.65 g (0.05 mol) of carbamic acid-β-methoxyethyl ester and 0.15 g of zinc chloride were heated to 50° C. 8.8 g (0.05 mol) of 6-isocyanato-caproyl chloride were added dropwise to the resulting melt. Nitrogen was passed through the mixture while it was heated to 60° C. for 3 hours and then to 100° C. for 26 hours. The reaction was then terminated (IR control). The mixture was cooled, taken up in 100 ml of toluene and decanted to remove insoluble constituents; the toluene was removed under vacuum. 11 g of a colorless oil was obtained, which solidified to a waxy solid. Yield: 11 g=85%

Provenance & Evidence