HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Dibromopropane → 1-(3-Bromopropoxy)-2-propylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Dibromopropane | HCID 8001 | — |
| Reactant | 2-Propylphenol | HCID 12570 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Catalyst | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-(3-Bromopropoxy)-2-propylbenzene | HCID 12355864 | — |
Reaction Steps
The title compound was prepared according to the procedure of Example 7 using 2-n propylphenol (30 g, 0.22 mol) in methylene chloride (400 ml), sodium hydroxide (18.8 g, 0.44 mol) in water (400 ml), 1,3-dibromopropane (100 g, 1 mol) and tetra-n butylammonium bisulfate (80 g, 0.22 mol). Distillation of the crude product yielded 55 g (75%) of pure material, b.p 85°-87° (0.1 mm Hg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04923891 |
| Source dataset | uspto-grants-1990_05 |
| ORD ID | ord-92031f1746d54338a2f060d06b8fcc23 |
| Source note | uspto-grants-1990_05 |