tert-Butyldimethylsilyl chloride → (2-Azidoethoxy)(tert-butyl)dimethylsilane

HRID 1650332Notes

Reaction equation

[N:1]([CH2:4][CH2:5][OH:6])=[N+:2]=[N-:3].[C:7]([Si:11](Cl)([CH3:13])[CH3:12])([CH3:10])([CH3:9])[CH3:8]>>[N:1]([CH2:4][CH2:5][O:6][Si:11]([C:7]([CH3:10])([CH3:9])[CH3:8])([CH3:13])[CH3:12])=[N+:2]=[N-:3]

Participants

Reactant 2

HCID 28928tert-Butyldimethylsilyl chloride

HCID 1231182-Azidoethanol

Product 1

HCID 14024254(2-Azidoethoxy)(tert-butyl)dimethylsilane

Procedure

protecting the hydroxy group of 2-azidoethanol with tert-butylchloro-dimethylsilane to produce 1-azido-2-(tertbutyl-dimethylsiloxy)ethane;

Sources & evidence

ORD record: ord-ef486c2e10704a8b93c18047e32786ac
Source dataset: uspto-grants-1990_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04923970

Reaction notes

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