Stannane, tributyl-3-thienyl- → HCID 20079868, compound

HRID 1654236Notes

Reaction equation

HRID 1654236 reaction equation
Br[C:2]1[CH:3]=[C:4]([S:8][CH:9]([CH3:14])[C:10]([O:12]C)=[O:11])[CH:5]=[CH:6][CH:7]=1.C([Sn](CCCC)(CCCC)[C:20]1[CH:24]=[CH:23][S:22][CH:21]=1)CCC.BrC1C=CC=CC=1CC(OC)=S>>[S:22]1[CH:23]=[CH:24][C:20]([C:2]2[CH:3]=[C:4]([S:8][CH:9]([CH3:14])[C:10]([OH:12])=[O:11])[CH:5]=[CH:6][CH:7]=2)=[CH:21]1

Participants

4

Reactant 3

HCID 10959689Stannane, tributyl-3-thienyl-HCID 20079893HCID 20079893, compoundHCID 54200479HCID 54200479, compound

Product 1

HCID 20079868HCID 20079868, compound

Procedure

The same procedure as in Reference Example 6 was carried out using methyl 2-(3-bromophenylthio)propionate and tributyl(3-thienyl)tin in place of the starting methyl 2-bromophenylthioacetate and tributylphenylthin to give 2-[3-(3-thienyl)phenylthio]propionic acid.

Sources & evidence

ORD record
ord-e7804765835241aa98936af21b3d5a7e
Source dataset
uspto-grants-1995_04
Patent number
US05405873

Reaction notes

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