HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 21783200, compound → HCID 70071916, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 21783200 | HCID 21783200 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 70071916 | HCID 70071916 | 94.4% |
Reaction Steps
A mixture of 5.0 g of cis-N-phenethyl-1,2,3,6-tetrahydrophthalimide (prepared by the method of Example 1), 0.5 g of chlorotris(triphenylphosphine)rhodium and 50 mL of p-xylene was heated under reflux for 48 hours. Removal of the solvent and short-path distillation of the residue (150° bath temperature, 0.001 mm) gave 4.72 g of cis-N-phenethyl-1,2,3,4-tetrahydrophthalimide containing 12% of unrearranged starting material.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05409929 |
| Source dataset | uspto-grants-1995_04 |
| ORD ID | ord-39dc0a149b5e43acb9324cfdc7536e7b |
| Source note | uspto-grants-1995_04 |