HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → 4-Butoxy-beta,beta-di(methylsulfonyl)styrene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | di(methylsulfonyl)methane | HCID 240586 | — |
| Reactant | N-(4-butoxybenzylidene)aniline | HCID 20077676 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | 4-Butoxy-beta,beta-di(methylsulfonyl)styrene | HCID 20077673 | 54.1% |
Reaction Conditions
| Temperature | 120 °C |
|---|
Reaction Steps
A mixture of 2.5 g (0.01 mol) of N-(4-butoxybenzylidene)aniline, 1.9 g (0.011 mol) of di(methylsulfonyl) methane, 1.1 mL of acetic anhydride, and 60 mL of p-xylene were heated at 120° C. for 3 days. Upon cooling, the contents of the reaction were chromatographed on silica gel, using dichloromethane as the eluent. Crystallization from toluene afforded 1.8 g (54%) of (6) as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05410630 |
| Source dataset | uspto-grants-1995_04 |
| ORD ID | ord-7e4e9a3cea324d93af09c4795be2e6d8 |
| Source note | uspto-grants-1995_04 |