HCID 10920955, compound → HCID 14917577, compound

HRID 1655705Notes

Reaction equation

HRID 1655705 reaction equation
C(SC1CCCCC=1)CCC.C(SC(C)=C)C.[CH2:18]([S:20][C@@:21]1([CH3:37])[CH2:24][C@@H:23]([C:25]([O:27][CH3:28])=[O:26])[C@@H:22]1[C:29]([N:31]1[CH2:35][CH2:34][O:33][C:32]1=[O:36])=[O:30])[CH3:19]>>[CH2:18]([S:20][C@:21]1([CH3:37])[CH2:24][C@@H:23]([C:25]([O:27][CH3:28])=[O:26])[C@@H:22]1[C:29]([N:31]1[CH2:35][CH2:34][O:33][C:32]1=[O:36])=[O:30])[CH3:19]

Participants

4

Reactant 3

HCID 10920955HCID 10920955, compoundHCID 13572265HCID 13572265, compoundHCID 22847894HCID 22847894, compound

Product 1

HCID 14917577HCID 14917577, compoundYield 70%

Procedure

The procedure of Example 2-1 was repeated except that the 1-n-butylthiocyclohexene was replaced with 2-ethylthiopropene. Thus a mixture of (1S,2R,3R)-1-ethylthio-3-methoxycarbonyl-1-methyl-2-(oxazolidin-2-on-3-yl)carbonylcyclobutane and (1R,2R,3R)-1-ethylthio-3-methoxycarbonyl-1-methyl-2-(oxazolidin-2-on-3-yl)carbonylcyclobutane (72:28, 70%) was obtained.

Sources & evidence

ORD record
ord-8272dd1dca704f1385701b8f4adb5622
Source dataset
uspto-grants-1993_10
Patent number
US05250697

Reaction notes

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