Methyl iodide → HCID 15079203, compound

HRID 1655940Notes

Reaction equation

HRID 1655940 reaction equation
[C:1]1(=[O:17])[N:5]([CH2:6][C:7]2[NH:11][N:10]=[N:9][N:8]=2)[C:4](=[O:12])[C:3]2=[CH:13][CH:14]=[CH:15][CH:16]=[C:2]12.[CH3:18]CCC[Sn](O[Sn](CCCC)(CCCC)CCCC)(CCCC)CCCC.CI>>[CH3:18][N:11]1[C:7]([CH2:6][N:5]2[C:4](=[O:12])[C:3]3=[CH:13][CH:14]=[CH:15][CH:16]=[C:2]3[C:1]2=[O:17])=[N:8][N:9]=[N:10]1

Participants

4

Reactant 3

HCID 6328Methyl iodideHCID 16682746Bis(tributyltin) oxideHCID 178514972HCID 178514972, compound

Product 1

HCID 15079203HCID 15079203, compound

Procedure

A mixture of 5-phthalimidomethyltetrazole (5 g; J. Org. Chem., 1959, 24, 1643), bis(tributyltin) oxide (11 ml) and methyl iodide (9 ml) was stirred vigorously at laboratory temperature for 3 days. The mixture was evaporated to dryness and the residue was washed with hexane and then triturated under ethanol. There was thus obtained as a white solid 1-methyl-5-phthalimidomethyltetrazole (3.1 g).

Workup

  1. customThe mixture was evaporated to dryness
  2. washthe residue was washed with hexane
  3. customtriturated under ethanol

Sources & evidence

ORD record
ord-78e0f2e31885461d83d1d3bb611b95f0
Source dataset
uspto-grants-1993_10
Patent number
US05252573

Reaction notes

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