3,5,5-Trimethylhexanal → 2,2,4,9,11,11-Hexamethyl-6-dodecanol

HRID 1656665Notes

Reaction equation

HRID 1656665 reaction equation
BrCCC(C)CC(C)(C)C.CC(CC(C)(C)C)CC=O.[CH3:21][C:22]([CH3:46])([CH2:24][CH:25]([CH3:45])[CH2:26][CH:27]([O:37]C(N1C=NC=N1)=O)[CH2:28][CH2:29][CH:30]([CH3:36])[CH2:31][C:32]([CH3:35])([CH3:34])[CH3:33])[CH3:23]>[Cu]>[CH3:46][C:22]([CH3:23])([CH2:24][CH:25]([CH3:45])[CH2:26][CH:27]([OH:37])[CH2:28][CH2:29][CH:30]([CH3:36])[CH2:31][C:32]([CH3:35])([CH3:34])[CH3:33])[CH3:21]

Participants

5

Reactant 3

HCID 215743,5,5-TrimethylhexanalHCID 1428001-Bromo-3,5,5-trimethylhexaneHCID 539365921-[2,2,4,9,11,11-Hexamethyl-6-dodecyloxycarbonyl]-1,2,4-triazole

Product 1

HCID 197887602,2,4,9,11,11-Hexamethyl-6-dodecanol

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

2,2,4,9,11,11-Hexamethyl-6-dodecanol (b.p. 104°-110° at 0.18 mm of mercury pressure) was prepared by reacting 1-bromo-3,5,5-trimethylhexane with 3,5,5-trimethylhexanal and converted into 1-[2,2,4,9,11,11-hexamethyl-6-dodecyloxycarbonyl]-1,2,4-triazole of formula: ##STR17## following the procedures of Example 18. This compound was evaluated as an extractant for copper by the procedure of Example 1 and the results are presented in Table 2.

Sources & evidence

ORD record
ord-dee36526de5e407a8059d0c6bf8d77fe
Source dataset
uspto-grants-1993_10
Patent number
US05254695

Reaction notes

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