HRID1657130

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID61221

Dibutylstannane oxide

C8H18OSn

$结构：CCCCCC[C@@H](O)C/C=C\CCCCCCCC(=O)O$

HCID643684

(9Z,12R)-12-Hydroxyoctadec-9-enoic acid

C18H34O3

PRODUCTS

生成物

$结构：CCCCCC[C@@H](O)C/C=C\CCCCCCCC(=O)[O-].CCCCCC[C@@H](O)C/C=C\CCCCCCCC(=O)[O-].CCC[CH2][Sn+2][CH2]CCC$

HCID86747340

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A mixture of dibutyltin oxide, 31.2 g (0.125 mole), ricinoleic acid, 74.25 g (0.25 mole), and 250 ml toluene were mixed and reacted as described in Example 1. Removal of toluene yielded 120 g (944 yield) of dibutyltin bis-ricinoleate, a yellow viscous liquid.

WORKUP

后处理

additionwere mixed
customreacted
customRemoval of toluene

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d98e29febf974c5b8e5f8a26b881742a
来源数据集: uspto-grants-1993_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05256704
来源说明: uspto-grants-1993_10

反应 SMILES

[CH2:1]([Sn:5](=O)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[C:11]([OH:31])(=[O:30])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]/[CH:19]=[CH:20]\[CH2:21][C@@H:22]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[OH:23]>C1(C)C=CC=CC=1>[C:11]([O-:31])(=[O:30])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]/[CH:19]=[CH:20]\[CH2:21][C@@H:22]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[OH:23].[C:11]([O-:31])(=[O:30])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]/[CH:19]=[CH:20]\[CH2:21][C@@H:22]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[OH:23].[CH2:1]([Sn+2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]