HCID 22848237, compound → 5,5-Diphenyl-2-cyclopenten-1-ol

HRID 1657291Notes

Reaction equation

HRID 1657291 reaction equation
O1[C@@H:6]2[C@H:2]1[C@H:3]([OH:19])[C:4]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[CH2:5]2>CO>[C:7]1([C:4]2([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[CH:3]([OH:19])[CH:2]=[CH:6][CH2:5]2)[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=1

Participants

3

Reactant 1

HCID 22848237HCID 22848237, compound

Product 1

HCID 100371165,5-Diphenyl-2-cyclopenten-1-ol

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

(+)-rel-(1R,2R,3S)-2,3-epoxy-5,5-diphenylcyclopentan-1-ol [(+) isomer rich mixture; [α]D22 =+45.34° (C=0.743, CH3OH)] (-)-5,5-diphenyl-2-cyclopenten-1-ol were obtained according to a similar manner to that of Preparation 20.

Sources & evidence

ORD record
ord-d70cd63c911444a989c1e6903f649520
Source dataset
uspto-grants-1993_10
Patent number
US05256824

Reaction notes

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