HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium → 1-Oxo-2-{[(2,3,6-trimethylphenyl)methyl]sulfanyl}-1lambda~5~-pyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | 1-(Bromomethyl)-2,3,4-trimethylbenzene | HCID 9990781 | — |
| Reactant | HCID 178526253 | HCID 178526253 | — |
| Product | 1-Oxo-2-{[(2,3,6-trimethylphenyl)methyl]sulfanyl}-1lambda~5~-pyridine | HCID 54017011 | 50% |
Reaction Steps
The intermediate 2-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide is prepared from α2 -bromoprehnitene with 2-mercaptopyridine N-oxide, sodium salt by the procedure described in Example 2. Yield 50% theory. Melting point 108° - 110°C. Structure confirmed by IR and NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03960542 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-f74bcc2bc54b429a8fcc3cf1c66832ae |
| Source note | uspto-grants-1976_06 |