Sodium Hydroxide → HCID 178519396, compound

HRID 1657508Notes

Reaction equation

HRID 1657508 reaction equation
[C:1]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]([C-:16]1[CH:20]=[CH:19][CH:18]=[CH:17]1)=[O:15])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26].[OH-].[Na+]>C(O)C>[C-:16]1([C:14]([CH:13]2[CH2:12][CH2:11][CH2:10][CH2:9][C:1]2([OH:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[O:15])[CH:17]=[CH:18][CH:19]=[CH:20]1.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 178520604HCID 178520604, compound

Product 1

HCID 178519396HCID 178519396, compoundYield 47%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

6-Benzoylhexanoylferrocene [2.91g; 7.5 mmole] was dissolved in a solution of sodium hydroxide [0.3g; 7.5 mmole] in ethanol [100 ml ] and stirred at room temperature for 16 hours. Filtration and recrystallization from cyclohexanone gave the desired product [1.3g; 47%] mp 172°-3°C.

Workup

  1. filtrationFiltration and recrystallization from cyclohexanone

Sources & evidence

ORD record
ord-64bf5601722947ba8f2586ea03bd4f2d
Source dataset
uspto-grants-1976_06
Patent number
US03960911

Reaction notes

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