HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl cyanoformate → HCID 54377216, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl cyanoformate | HCID 69336 | — |
| Reactant | Acetic acid, azido-, ethyl ester | HCID 69480 | — |
| Product | HCID 54377216 | HCID 54377216 | 98% |
Reaction Steps
A mixture of ethyl azidoacetate (13.1 grams, 98.5 percent pure, 0.1 mole) and ethyl cyanoformate (20.0 grams, distilled, 0.2 mole) was heated in an oil bath at 110°-111°C. for 24 hours. Removal of excess ethyl cyanoformate in vacuo gave 22.25 grams (98% of theoretical yield) of ethyl 5-(ethoxycarbonyl)-1-H-tetrazole-1-acetate which was shown to be 91% pure by nuclear magnetic resonance.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03962272 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-b77760c7997048dd8df3a9e8af777c26 |
| Source note | uspto-grants-1976_06 |