HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 3,5-Diethylnitrobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Phosphinic Acid | HCID 4124402 | — |
| Reactant | 2,6-Diethyl-4-nitroaniline | HCID 8142677 | — |
| Reactant | Sodium Nitrite | HCID 23668193 | — |
| Solvent | Water | HCID 962 | — |
| Product | 3,5-Diethylnitrobenzene | HCID 14595943 | — |
Reaction Steps
A solution of 19.4 parts of 2,6-diethyl-4-nitroaniline in 40 parts by volume of concentrated hydrochloric acid is diluted with 80 parts of water and added to 100 parts of ice. A solution of 7 parts of sodium nitrite in 15 parts of water is added and the filtered diazonium solution treated with 150 parts by volume of 50% hypophosphorous acid and kept cold for 24 hours. The 3,5-diethylnitrobenzene which separates is extracted with ether and distilled, b.p. 190°/20mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03962307 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-82c96d0ba24a455aa09566e9fa7c33d1 |
| Source note | uspto-grants-1976_06 |