2-Nonen-1-ol, (2Z)- → (Z)-non-2-enal

HRID 1657946Notes

Reaction equation

HRID 1657946 reaction equation
[CH2:1]([OH:10])/[CH:2]=[CH:3]\[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]>CCOCC.[O-2].[O-2].[Mn+4]>[CH:1](=[O:10])/[CH:2]=[CH:3]\[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

4

Reactant 1

HCID 53650272-Nonen-1-ol, (2Z)-

Product 1

HCID 5354833(Z)-non-2-enal

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 3283Diethyl EtherSolvent

Procedure

Cis-2-nonenol (5 g, mole) is stirred with manganese dioxide (50 g, mole) in ether (250 ml) at room temperature for 1 hour. The mixture is filtered, ether removed, and the residue distilled to give cis-2-nonenal.

Workup

  1. filtrationThe mixture is filtered
  2. customether removed
  3. distillationthe residue distilled

Sources & evidence

ORD record
ord-adf1a6b11a3f4f42be911cb5a07f60ed
Source dataset
uspto-grants-1976_06
Patent number
US03962321

Reaction notes

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