p-nitrophenol sodium salt → 3-Nitroanisole

HRID 1658186Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([O-:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Na+].[N+]([C:15]1C=CC([O-])=CC=1)([O-])=O.[Na+]>>[N+:1]([C:4]1[CH:5]=[C:6]([O:10][CH3:15])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

Participants

Reactant 2

HCID 13214p-nitrophenol sodium salt

HCID 101286967CID 101286967

Product 1

HCID 111403-NitroanisoleYield 85%

Procedure

The procedure and reactants of Example 1 were used except that sodium m-nitrophenolate was substituted for sodium p-nitrophenolate. 0.6 grams of m-nitroanisole (about 85 percent) were obtained.

Sources & evidence

ORD record: ord-054e1fb30a5b4edca21a6c84348fffe2
Source dataset: uspto-grants-1976_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03963698

Reaction notes

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