HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroxylamine → N-hydroxyhexadecanamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroxylamine | HCID 787 | — |
| Reactant | Ethyl palmitate | HCID 12366 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | HCID 178515546 | HCID 178515546 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | N-hydroxyhexadecanamide | HCID 414280 | 85% |
Reaction Steps
14.2 g. of ethyl palmitate and 2 g. of hydroxylamine are reacted at room temperature in 300 ml. of ethanol in the presence of 1.7 g. of the sodium salt of 2-hydroxyquinoline. The reaction is complete in 5 hours, and 11.7 g. of palmitohydroxamic acid are obtained (yield: 85%), m.p. 100° - 101°C. after recrystallization from ethanol-petroleum ether(1:1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03963728 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-63aedffb4a784800a57e2bbca8be9c28 |
| Source note | uspto-grants-1976_06 |