HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → 5-[(4-Methylphenyl)sulfanyl]-2-nitroaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | 4-Methylbenzenethiol | HCID 7811 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 5-Chloro-2-nitroaniline | HCID 74218 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5-[(4-Methylphenyl)sulfanyl]-2-nitroaniline | HCID 20362819 | — |
Reaction Steps
A mixture of 4.1 g. potassium carbonate, 3.7 g. p-thiocresol and 5.1 g. 2-amino-4-chloro-1-nitrobenzene in 20 ml. dimethylformamide is stirred under nitrogen for 20 hours at 20°-25°C, water is added and the product filtered off. Recrystallization from methanol gives 2-amino-4-(p-methylphenylthio)-1-nitrobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03965113 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-cc5d21d9b0a8418eb058d712bf6d875e |
| Source note | uspto-grants-1976_06 |