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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1658675Generated: October 30, 2026

(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → D-(-)-Fructose

https://huagongshe.com/reaction/1658675

Reaction equation

Participants

RoleNameHCIDCharge
Reactant(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 107526—
ReactantMagnesium ChlorideHCID 5360315—
CatalystCobalt(II) chlorideHCID 24288—
ProductD-(-)-FructoseHCID 5984—

Reaction Steps

Two series of four glucose-containing liquor samples (mother liquor from primary dextrose crystallization, 90DE) were prepared containing 0.005M magnesium chloride and 0.001M cobalt chloride. Series A contained 53.4 percent dry substance, and Series B contained 56.7 percent dry substance. To the samples, were added various quantities of the air-dried filter cake of example I and sulfite salts. The isomerizations were carried out at 70° C. for various times under an atmosphere of nitrogen. The color and fructose formed during the isomerization reactions were determined and are shown below in table III.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUSRE028885
Source datasetuspto-grants-1976_06
ORD IDord-fcb996a96b504caca31d40f62962263e
Source noteuspto-grants-1976_06