HuagongsheHuagongshe Chemistry Print Report · For research reference only
(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → D-(-)-Fructose
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | Magnesium Chloride | HCID 5360315 | — |
| Catalyst | Cobalt(II) chloride | HCID 24288 | — |
| Product | D-(-)-Fructose | HCID 5984 | — |
Reaction Steps
Two series of four glucose-containing liquor samples (mother liquor from primary dextrose crystallization, 90DE) were prepared containing 0.005M magnesium chloride and 0.001M cobalt chloride. Series A contained 53.4 percent dry substance, and Series B contained 56.7 percent dry substance. To the samples, were added various quantities of the air-dried filter cake of example I and sulfite salts. The isomerizations were carried out at 70° C. for various times under an atmosphere of nitrogen. The color and fructose formed during the isomerization reactions were determined and are shown below in table III.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | USRE028885 |
| Source dataset | uspto-grants-1976_06 |
| ORD ID | ord-fcb996a96b504caca31d40f62962263e |
| Source note | uspto-grants-1976_06 |