Bromotriphenylmethane → 5,5-Dimethyl-1-iodo-3-triphenylmethoxy-trans-1-octene

HRID 1659047노트

반응식

HRID 1659047 반응식
[CH3:1][C:2]([CH3:12])([CH2:9][CH2:10][CH3:11])[CH2:3][CH:4]([OH:8])/[CH:5]=[CH:6]/[I:7].[C:13]1([C:19](Br)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH3:1][C:2]([CH3:12])([CH2:9][CH2:10][CH3:11])[CH2:3][CH:4]([O:8][C:19]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([C:26]1[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1)[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)/[CH:5]=[CH:6]/[I:7]

참가 물질

3

반응물 2

HCID 11692BromotriphenylmethaneHCID 204656065,5-Dimethyl-1-iodo-trans-octen-3-ol

생성물 1

HCID 204657245,5-Dimethyl-1-iodo-3-triphenylmethoxy-trans-1-octene

실험 절차

Treatment of 6.0 g. of 5,5-dimethyl-1-iodo-trans-1-octen-3-ol (Example 1000) with 6.9 g. of triphenylmethyl bromide in 30 ml. of pyridine and purification on Florisil, all as described in Example 728 gives the title compound.

후처리

  1. customof pyridine and purification on Florisil

출처 및 근거

ORD 기록
ord-5f87bf19d734403a82b6aa5e391b7428
출처 데이터셋
uspto-grants-1976_06
특허 번호
US03966773

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