Methanethiol → HCID 54522754, compound

HRID 1659193Notes

Reaction equation

HRID 1659193 reaction equation
[CH3:1][S:2][C:3]1[CH:10]=[CH:9][CH:8]=[C:7]([N+:11]([O-])=O)[C:4]=1[C:5]#[N:6].[N+](C1C=CC=C([N+]([O-])=O)C=1C#N)([O-])=[O:15].CS>[Ni]>[NH2:11][C:7]1[CH:8]=[CH:9][CH:10]=[C:3]([S:2][CH3:1])[C:4]=1[C:5]([NH2:6])=[O:15]

Participants

5

Reactant 3

HCID 878MethanethiolHCID 520718DinitrobenzonitrileHCID 12715768HCID 12715768, compound

Product 1

HCID 54522754HCID 54522754, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

2-Amino-6-(methylthio) benzamide is prepared by Raney nickel reduction of 2-(methylthio)-6-nitrobenzonitrile which is prepared from 2,6-dinitrobenzonitrile and methylmercaptan following the procedure set forth in Example 75.

Sources & evidence

ORD record
ord-fc7cd85436e54d2d8bb691c0232cd0ec
Source dataset
uspto-grants-1976_06
Patent number
US03966965

Reaction notes

Loading…