HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → Methyl octyl sulfide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | 1-Octene | HCID 8125 | — |
| Reactant | Dimethyl Disulfide | HCID 12232 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | Methyl octyl sulfide | HCID 77289 | 64.8% |
Reaction Steps
The procedure of Example 1 was repeated using dimethyldisulphide (96 mg; 1.02 mmol) and 1-octene (358 mg; 3.19 mmol) in acetonitrile (15 ml) at +1.20 V until 2 coulomb equivalents of charge had been passed. After the addition of water and extraction with diethyl ether, there was obtained 106 mg of methylthio-octane. Mass Spec. m/e 217 (M+) and 44 (100%). I.R. 3300 and 1650 cm-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04304642 |
| Source dataset | uspto-grants-1981_12 |
| ORD ID | ord-4412bfae539948fd8cc68a4008a25a58 |
| Source note | uspto-grants-1981_12 |