HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl acetoacetate → HCID 54442326, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl acetoacetate | HCID 7757 | — |
| Reactant | 2-Propylidenecyclopentanone | HCID 3016195 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 54442326 | HCID 54442326 | 53.3% |
Reaction Steps
The procedure of Example 1 is repeated with 19.5 g (0.16 mol) of propylidene cyclopentanone, 0.46 g (0.02 g-atom) of sodium, 21 g (0.18 mol) of methyl acetoacetate and 100 ml of methanol. Fractional distillation yields 14 g (bp 95°-102° C. at 0.5 mm) of 5-ethylbicyclo [4.3.0] non-1-en-3-one having the structure: ##STR8##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04304944 |
| Source dataset | uspto-grants-1981_12 |
| ORD ID | ord-6b088e2e29e748ecaaa80e0ee93ac376 |
| Source note | uspto-grants-1981_12 |