Sodium Hydroxide → HCID 53848484, compound

HRID 1659698Notes

Reaction equation

C[O:2][C:3](=[O:17])[C:4](=[N:14][O:15][CH3:16])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[C:7]([Cl:13])[CH:6]=1.[OH-].[Na+]>>[CH3:16][O:15][N:14]=[C:4]([C:5]1[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[C:7]([Cl:13])[CH:6]=1)[C:3]([OH:17])=[O:2]

Participants

Reactant 2

HCID 14798Sodium Hydroxide

HCID 54489693HCID 54489693, compound

Product 1

HCID 53848484HCID 53848484, compoundYield 101.8%

Procedure

Methyl-2-methoxyimino-2-(3-chloro-4-methoxyphenyl)acetate (syn isomer) (2.7 g.) and a 2 N aqueous solution of sodium hydroxide (10.6 ml.) were treated according to a similar manner to that of Preparation (5-3) (c) to give crystals of 2-methoxyimino-2-(3-chloro-4-methoxyphenyl)acetic acid (syn isomer) (2.6 g.), mp 133° to 135° C. (dec.).

Sources & evidence

ORD record: ord-62e7bf20d03d480c9402d43801a1d4d9
Source dataset: uspto-grants-1981_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04304770

Reaction notes

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