2-Cyclohexen-1-one → 3-[2-(Benzyloxy)-4-(2-methyloctan-2-yl)phenyl]cyclohexan-1-one

HRID 1660048Notes

Reaction equation

HRID 1660048 reaction equation
[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:22])([CH3:21])[CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH:12]=[CH:11][C:10]=1[CH:23]1[CH2:28][CH2:27][CH2:26][C:25](=[O:29])[CH2:24]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:30](OC1C=C(C(C)(CCCCC)C)C=CC=1Br)C1C=CC=CC=1.C1(=O)CCCC=C1>>[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:22])([CH3:21])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:30])[CH:12]=[CH:11][C:10]=1[CH:23]1[CH2:28][CH2:27][CH2:26][C:25](=[O:29])[CH2:24]1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 3

HCID 135942-Cyclohexen-1-oneHCID 20496828HCID 20496828, compoundHCID 20496853HCID 20496853, compound

Product 1

HCID 127881893-[2-(Benzyloxy)-4-(2-methyloctan-2-yl)phenyl]cyclohexan-1-one

Procedure

3-[2-Benzyloxy-4-(1,1-dimethylhexyl)phenyl]cyclohexanone as an oil (11.0 g., 35%) from 2-(3-benzyloxy-4-bromophenyl)-2-methylheptane (30.2 g., 0.0806 mole) and 2-cyclohexen-1-one (8.5 g., 0.0886 mole).

Sources & evidence

ORD record
ord-a444bce3a3f0470181838415119eb50f
Source dataset
uspto-grants-1981_12
Patent number
US04306097

Reaction notes

Loading…