5-(2-Benzyloxy-4-(1,1-dimethylheptyl)phenyl)-3-methoxy-6-methyl-2-cyclohexen-1-one → 5-[2-Benzyloxy-4-(1,1-dimethylheptyl)phenyl]-3,4-dimethyl-2-cyclohexen-1-one

HRID 1660070Notes

Reaction equation

HRID 1660070 reaction equation
[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:23])([CH3:22])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH:12]=[CH:11][C:10]=1[CH:24]1[CH:29]([CH3:30])[C:28](=O)[CH:27]=[C:26]([O:32]C)[CH2:25]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:34][Mg]I>>[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:22])([CH3:23])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH:12]=[CH:11][C:10]=1[CH:24]1[CH2:25][C:26](=[O:32])[CH:27]=[C:28]([CH3:34])[CH:29]1[CH3:30])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 204968155-(2-Benzyloxy-4-(1,1-dimethylheptyl)phenyl)-3-methoxy-6-methyl-2-cyclohexen-1-oneHCID 178418373HCID 178418373, compound

Product 1

HCID 204967985-[2-Benzyloxy-4-(1,1-dimethylheptyl)phenyl]-3,4-dimethyl-2-cyclohexen-1-one

Procedure

Following the procedure of Example 1, 5-[2-benzyloxy-4-(1,1-dimethylheptyl)phenyl]-3-methoxy-6-methyl-2-cyclohexen-1-one is reacted via the Grignard reaction with methyl magnesium iodide to give the title compound.

Sources & evidence

ORD record
ord-e4cb521db4d7415f9ab0e9716390000c
Source dataset
uspto-grants-1981_12
Patent number
US04306097

Reaction notes

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