HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphonium, hexyltriphenyl-, bromide (1:1) → 1-Benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphonium, hexyltriphenyl-, bromide (1:1) | HCID 2724569 | — |
| Reactant | 2-(3-(Benzyloxy)phenyl)-2-methylpropanal | HCID 19855359 | — |
| Product | 1-Benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene | HCID 54246232 | 70% |
Reaction Steps
Similarly, 1-benzyloxy-3-(1,1-dimethyloct-2-enyl)benzene (13.5 g., 70%) was prepared from 15.75 g. (0.062 mol.) of 2-(3-benzyloxyphenyl)-2-methyl-propionaldehyde and 37.5 g. (0.0899 mol.) of hexyltriphenylphosphonium bromide. The product was an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04306097 |
| Source dataset | uspto-grants-1981_12 |
| ORD ID | ord-c3d8ffcb47284851abc97b55d7f727a7 |
| Source note | uspto-grants-1981_12 |