Thiophenol → HCID 12800049, compound

HRID 1660416Notes

Reaction equation

HRID 1660416 reaction equation
[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[K+].[Cl:10][C:11]1[CH:12]=[CH:13][C:14]2[S:18][C:17](=[O:19])[N:16]([CH2:20][C:21](Cl)=[O:22])[C:15]=2[CH:24]=1>CC(C)=O>[Cl:10][C:11]1[CH:12]=[CH:13][C:14]2[S:18][C:17](=[O:19])[N:16]([CH2:20][C:21](=[O:22])[S:7][C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)[C:15]=2[CH:24]=1

Participants

5

Reactant 3

HCID 7969ThiophenolHCID 14797Potassium HydroxideHCID 14221220HCID 14221220, compound

Product 1

HCID 12800049HCID 12800049, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A charge containing 0.1 moles of benzenethiol, 0.1 moles of 85% potassium hydroxide and 250 ml of acetone is stirred as in Example 1. To this mixture, 0.1 moles of 5-chloro-2-oxo-3-benzothiazolineacetyl chloride is added in one portion. The remaining steps of Example 1 are then followed. Analytical data is summarized in Table I, below.

Sources & evidence

ORD record
ord-6106b66c7b634080bf8f43a3c575f78d
Source dataset
uspto-grants-1981_12
Patent number
US04308052

Reaction notes

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