HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Cyclohexen-1-one, 4,4-dimethyl- → Cyclohexanone, 4,4-dimethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Cyclohexen-1-one, 4,4-dimethyl- | HCID 136839 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Pentane | HCID 8003 | — |
| Product | Cyclohexanone, 4,4-dimethyl- | HCID 138166 | 98.3% |
Reaction Steps
4,4-dimethyl-cyclohexen-1-one (5 g, 40.3 mmol) were placed in a hydrogen reaction vessel and n-pentane (15 ml) was added, and Pd/C (500 mg) was added thereto. The hydrogen reaction vessel was pressurized with hydrogen (25 psi), and the reaction was conducted for 30 minutes. After completing the reaction, the solid like material was filtered through Celite and the filtrate was concentrated in vacuo to give the title compound (5 g, 98%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08039622B2 |
| Source dataset | uspto-grants-2011_10 |
| ORD ID | ord-9aad7002ed9e4f82b31ddefe6ba372b6 |
| Source note | uspto-grants-2011_10 |