HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → Diethenyl benzene-1,4-dicarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Acetylene | HCID 6326 | — |
| Reactant | Terephthalic Acid | HCID 7489 | — |
| Catalyst | 14285-68-8 | HCID 498777 | — |
| Product | Diethenyl benzene-1,4-dicarboxylate | HCID 15374889 | — |
Reaction Steps
A mixture of 8.0 g of terephthalic acid (48 mmol), 0.10 g of Re2(CO)10 (0.15 mmol) and 17.3 g of toluene was subjected to vinylation at 140° C., a nitrogen pressure of 2 bar and an acetylene pressure of 18 bar for 6 h. Divinyl terephthalate was obtained, which was detectable by means of GC-MS analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08044233B2 |
| Source dataset | uspto-grants-2011_10 |
| ORD ID | ord-cdb6101b28e64e3fb355e06235d710be |
| Source note | uspto-grants-2011_10 |