HCID 10863545, compound → HCID 11021339, compound

HRID 1669928Notes

Reaction equation

HRID 1669928 reaction equation
[C:1]([O:5][C:6]([C:8]1([CH3:32])[CH2:12][O:11][S:10](=[O:14])(=[O:13])[N:9]1[CH:15](C1C=CC(OC)=CC=1)C1C=CC(OC)=CC=1)=[O:7])([CH3:4])([CH3:3])[CH3:2].C(OC(C1(C)COS(=O)N1C)=O)(C)(C)C>>[C:1]([O:5][C:6]([C:8]1([CH3:32])[CH2:12][O:11][S:10](=[O:13])(=[O:14])[N:9]1[CH3:15])=[O:7])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 10863545HCID 10863545, compoundHCID 11031843HCID 11031843, compound

Product 1

HCID 11021339HCID 11021339, compoundYield 94%

Procedure

The same reaction conditions used to obtain 14a were applied to 42 mg of 13b (0.18 mmol), providing 14b (42 mg, 94%) as a white solid: mp 54-55° C. (EtOAc/hexane); 1H NMR (CDCl3) δ1.50 (9H, s), 1.52 (3H, s), 2.93 (3H, s), 4.22 (1H, d, J=8.8), 4.88 (1H, d, J=8.8). Anal. (C9H17NO5S) C, H, N.

Workup

  1. customThe same reaction conditions

Sources & evidence

ORD record
ord-8f5b966b22964759b119327e384716d4
Source dataset
uspto-grants-2011_08
Patent number
US07989649B2

Reaction notes

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