Sodium Azide → HCID 86629036, compound

Participants

Reaction Steps

Following the general procedure for the preparation of azides of Description 16, 3-methylbutyl (2R)-4-[(3-chloropropyl)sulfonyloxy]-3,3-dimethyl-2-(phenylmethoxy)butanoate (29a) (0.32 g, 0.74 mmol) dissolved in 5 mL of anhydrous dimethyl sulfoxide (DMSO) was reacted with 0.11 g (1.5 mmol) of sodium azide (NaN3). After work-up, the crude material (29b) was used in the next step without further purification. MS (ESI) m/z 478.18 (M+Na)+.

Provenance & Evidence