Tetrahydrofuran → HCID 87941504, compound

Participants

Reaction Conditions

Reaction Steps

The title compound was synthesized according to a modified literature procedure.29 It should be noted that a mixture of the 2,8,14 and 2,8,15 isomers are formed. 5,6,11,12,17,18-Hexaazatrinaphthylene 2,8,14-tricarbonyl trichloride BK1—17 (2.28 g, 3.99 mmol) was dissolved in 80 ml dry THF and placed in a 100 ml three neck round bottom flask. 3,4,5-Tris(dodecanyloxy)benzoichydrazide SM6 (9.07 g, 13.2 mmol), dissolved in 200 ml THF, was placed in a dropping funnel. The apparatus was placed in a dewar flask (ice+H2O). The apparatus was degassed with argon. At a steady rate, SM6 solution was slowly added dropwise. The reaction mixture was stirred at 0° C. for two hours, after which 3 ml of pyridine were added and the solution was further stirred at room temperature overnight. Water (200 ml) was added to the reaction mixture upon which a dark solid formed. This solid (10.0 g, 99%) was filtered and dried. This compound was used with no further purification.

Provenance & Evidence