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HRID1673132

反应详情

EQUATION

反应方程式

HRID 1673132 的结构方程式

REACTANTS

反应物

2
结构：O=C(O)C[C@H](O)C(=O)O
HCID222656

(2S)-2-Hydroxybutanedioic acid

C4H6O5

结构：CC(C)(C)[Si](C)(C)O[C@@H](CCl)CC=O
HCID13963153

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](C)(C)O[C@H](CCl)CC=O
HCID13963152

未命名化合物

PROCEDURE

实验过程

(S)-3-(tert-Butyldimethylsilyloxy)-4-chlorobutanal was prepared by the same route as (R)-3-(tert-butyldimethylsilyloxy)-4-chlorobutanal starting from (S)-2-hydroxysuccinic acid. 1H NMR (400 MHz, CDCl3) δ 9.72 (dd, J=1.6, 2.2 Hz, 1H), 4.33-4.28 (m, 1H), 3.46 (dd, J=4.7, 11.1 Hz, 1H), 3.39 (dd, J=6.4, 11.1 Hz, 1H), 2.68 (dd, J=1.5, 4.7 Hz, 1H), 2.62 (dd, J=2.3, 6.8 Hz, 1H), 0.79 (s, 9H), 0.04 (s, 3H), 0.01 (s, 3H).