Hydrazine → HCID 178514341, compound

Participants

Reaction Conditions

Reaction Steps

To a stirred solution of 10-2 (0.5 g, 0.9 mMol) in anhydrous 1,4-dioxane (5 mL) was added hydrazine (0.56 mL, 17.8 mMol). The solution was heated to 100° C. in a microwave reactor for 20 minutes. The solvent was removed in vacuo and was dried azeotropically with toluene three times. The crude solid was triturated with a saturated NaHCO3 solution for 20 minutes. The suspension was filtered and washed with copious amounts of water. The solid was dried azeotropically with toluene three times to yield 10-3 as a brown solid. LC/MS (M+1) calculated: 555.6; observed: 555.2

Provenance & Evidence