Ethylamine → N-ethyl-2,6-dinitro-4-t-butylaniline

HRID 1678836Notes

Reaction equation

HRID 1678836 reaction equation
[CH2:1]([NH2:3])[CH3:2].[N+:4]([C:7]1[CH:12]=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[CH:10]=[C:9]([N+:17]([O-:19])=[O:18])[C:8]=1Cl)([O-:6])=[O:5]>>[CH2:1]([NH:3][C:8]1[C:9]([N+:17]([O-:19])=[O:18])=[CH:10][C:11]([C:13]([CH3:16])([CH3:14])[CH3:15])=[CH:12][C:7]=1[N+:4]([O-:6])=[O:5])[CH3:2]

Participants

3

Reactant 2

HCID 6341EthylamineHCID 751764-tert-Butyl-2,6-dinitrochlorobenzene

Product 1

HCID 20364246N-ethyl-2,6-dinitro-4-t-butylaniline

Procedure

Following the above procedure, two grams of a 70% aqueous solution of ethylamine was reacted with 2.6 grams (0.01 mole) of 2,6-dinitro-4-t-butylchlorobenzene to yield 2 grams of N-ethyl-2,6-dinitro-4-t-butylaniline as orange needles melting at 70°-73° C.

Sources & evidence

ORD record
ord-c51985d4c67b4249b0d167653f0cfac3
Source dataset
uspto-grants-1978_03
Patent number
US04077795

Reaction notes

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