1,3-Dioxolane → HCID 178489551, compound

HRID 1678990Notes

Reaction equation

HRID 1678990 reaction equation
[CH2:1]([O:8][CH:9]1[CH2:14][O:13][CH:12]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2OC)[O:11][CH2:10]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O:23]1CCO[CH2:24]1>>[CH3:24][O:23][C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=1[CH2:1][O:8][C@H:9]1[CH2:10][O:11][C@@H:12]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)[O:13][CH2:14]1

Participants

3

Reactant 2

HCID 125861,3-DioxolaneHCID 20364968HCID 20364968, compound

Product 1

HCID 178489551HCID 178489551, compound

Procedure

5-benzyloxy-2-(2-methoxyphenyl)-1,3-dioxane (b.p. 190°-195° C at 10-5 mm; VPC analysis indicated that it contained 14% cis, 31% trans, and 55% of the isomeric dioxolane);

Sources & evidence

ORD record
ord-4b8341b5a41b4223860ea7f80bbb9e85
Source dataset
uspto-grants-1978_03
Patent number
US04077982

Reaction notes

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