Acetic Acid → HCID 178526285, compound

HRID 1679099Notes

Reaction equation

HRID 1679099 reaction equation
[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[CH:5][C:3]=1[NH2:4].[CH2:9]([N+:13]([O-])=O)/[CH:10]=[N:11]\[OH:12].C(O)(=[O:18])C>>[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[CH:5][C:3]=1[N:4]1[N:13]=[C:9]([OH:18])[CH:10]=[N+:11]1[O-:12]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 72402-ChloroanilineHCID 58810166(NZ)-N-(2-nitroethylidene)hydroxylamine

Product 1

HCID 178526285HCID 178526285, compound

Procedure

100 g of oxime-hydrazone II (R = 2-chlorophenyl), prepared from diazotized 2-chloroaniline and methazonic acid, is stirred in 1000 ml of 90% acetic acid at room temperature. There are formed after a short time nitrous gases, and a dark clear solution is obtained. After 10 hours, the solution is concentrated by evaporation to dryness, and the residue is stirred into ether, filtered off under suction and dried.

Workup

  1. customThere are formed after a short time nitrous gases
  2. customa dark clear solution is obtained
  3. concentrationthe solution is concentrated by evaporation to dryness
  4. filtrationfiltered off under suction
  5. customdried

Sources & evidence

ORD record
ord-6299eff277be4c919f5e7364fa9663cc
Source dataset
uspto-grants-1978_03
Patent number
US04079063

Reaction notes

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