HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus trichloride → HCID 5363557, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus trichloride | HCID 24387 | — |
| Reactant | HCID 54179035 | HCID 54179035 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 5363557 | HCID 5363557 | — |
Reaction Steps
To 1-acetoxy-4-nitro-but-2-ene (4 g.) in 40 cc of methylenechloride and 40 cc of pyridine was added under ice cooling 4.4 cc of PCl3. The reaction was worked up after 1 hour stirring at room temperature. The crude product was purified by distillation and column chromatography. γ-Acetoxycrotononitrile was obtained as a colorless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04079076 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-cc5103333bea4bdabc9c07ef96c555fd |
| Source note | uspto-grants-1978_03 |