4,4'-Diphenylbenzophenone → 4-Biphenylyl-3-methylaminoprop-1-ene ene
Reaction equation
[Br-].[CH3:2][NH:3]CC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[C:25]1([C:45]2[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=2)[CH:30]=[CH:29][C:28]([C:31]([C:33]2C=CC(C3C=CC=CC=3)=C[CH:34]=2)=O)=[CH:27][CH:26]=1>>[C:25]1([C:45]2[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=2)[CH:30]=[CH:29][C:28]([CH:31]=[C:33]=[CH:34][NH:3][CH3:2])=[CH:27][CH:26]=1Participants
3
Procedure
β-Methylaminoethyltriphenylphosphonium bromide was reacted with di-4 -biphenylyl ketone by the method of Example 1 to give 1,1-di(4-biphenylyl-3-methylaminoprop-1-ene ene identical with that described in Example 4.
Sources & evidence
- ORD record
- ord-7fbdaab6c051403483f3f514170a68db
- Source dataset
- uspto-grants-1978_03
- Patent number
- US04079081
Reaction notes
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