4'-Chlorobiphenyl-4-carbonyl chloride → 4'-Chloro-4-biphenylyl 4-chlorophenyl ketone

HRID 1679160Notes

Reaction equation

HRID 1679160 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([C:14](Cl)=[O:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1>ClC1C=CC=CC=1>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([C:14]([C:5]3[CH:6]=[CH:7][C:2]([Cl:1])=[CH:3][CH:4]=3)=[O:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1

Participants

3

Reactant 1

HCID 98348144'-Chlorobiphenyl-4-carbonyl chloride

Product 1

HCID 203638444'-Chloro-4-biphenylyl 4-chlorophenyl ketone

Reagents, catalysts & solvents 1

HCID 7964ChlorobenzeneSolvent

Procedure

4'-Chlorobiphenyl-4-carboxylic acid chloride (Musante and Parrini, Gazz, Chim. ital., 1949, 49, 453) was reacted with chlorobenzene by the method of Example 7, to give 4-chlorophenyl 4'-chloro-4-biphenylyl ketone identical with that described in Example 8.

Sources & evidence

ORD record
ord-67aa4c021b094b0eb75c3950c76a0da8
Source dataset
uspto-grants-1978_03
Patent number
US04079081

Reaction notes

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