1-Butanol → HCID 23419109, compound

HRID 1679303Notes

Reaction equation

HRID 1679303 reaction equation
[N:1]1[P:6](Cl)(Cl)=[N:5][P:4](Cl)(Cl)=[N:3][P:2]=1(Cl)Cl.[CH2:13]([OH:17])[CH2:14][CH2:15][CH3:16]>N1C=CC=CC=1>[CH2:13]([O:17][P:2]1([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:3]=[P:4]([O:17][CH2:13][CH2:14][CH2:15][CH3:16])([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:5]=[P:6]([O:17][CH2:13][CH2:14][CH2:15][CH3:16])([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:1]=1)[CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 2631-ButanolHCID 220225Hexachlorocyclotriphosphazene

Product 1

HCID 23419109HCID 23419109, compoundYield 90%

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a chilled solution (0°-5° C.) of triphosphonitrilic chloride (0.018 mole) in 26 ml of pyridine, butanol (0.34 mole) was added. The mixture was stirred at room temperature overnight, diluted with petroleum ether and washed with dilute HCl, NaHCO3, and water successively. After removal of solvent, the product IIa was obtained in a yield of 90%. Found (and calcd. for C24H54N3O6P3 /M.W. 574): C 47.32 (50.25); H 9.00 (9.49); and N 7.71 (7.33).

Workup

  1. washwashed with dilute HCl, NaHCO3, and water successively
  2. customAfter removal of solvent
  3. customthe product IIa was obtained in a yield of 90%

Sources & evidence

ORD record
ord-be7096bb0f2e43f5b94261aa5e852a8f
Source dataset
uspto-grants-1978_03
Patent number
US04080361

Reaction notes

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