HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroform → N-[2-Nitro-4-(phenylmethanesulfinyl)phenyl]acetamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | N-[4-(Benzylsulfanyl)-2-nitrophenyl]acetamide | HCID 20362823 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | N-[2-Nitro-4-(phenylmethanesulfinyl)phenyl]acetamide | HCID 20362831 | — |
Reaction Steps
2.42 G. 1-acetamido-2-nitro-4-benzylthiobenzene in 25 ml. chloroform is treated at -20° to -15° C with 1.6 g. 40% peracetic acid in 2 ml. methanol. The mixture is allowed to warm slowly to room temperature, held for 6 hours and washed with sodium bisulfite solution and sodium bicarbonate solution, dried and stripped. The residue is recrystallized from methanol giving 1-acetamido-2-nitro-4-benzylsulfinylbenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04080461 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-71489e858a034260879f2a10660062c1 |
| Source note | uspto-grants-1978_03 |