HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 4-[(4-Methylphenyl)sulfanyl]benzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Potassium Bicarbonate | HCID 516893 | — |
| Reactant | 5-[(4-Methylphenyl)sulfanyl]-2-nitroaniline | HCID 20362819 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 4-[(4-Methylphenyl)sulfanyl]benzene-1,2-diamine | HCID 20362821 | — |
Reaction Steps
3.35 G. of 2-amino-4-(p-methylphenylthio)-1-nitrobenzene in 16 ml. concentrated hydrochloric acid and 16 ml. acetic acid is treated with 16 g. stannous chloride on the steam bath for 1 hour. The mixture is cooled, treated with an excess of potassium bicarbonate and extracted with chloroform. Evaporation of the chloroform leaves 1,2-diamino-4-(p-methylphenylthio)benzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04080461 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-2bc74785476741c09b5c51fed83fbd93 |
| Source note | uspto-grants-1978_03 |