HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 4-[(Methoxymethyl)sulfanyl]benzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 4-[(Methoxymethyl)sulfanyl]-2-nitroaniline | HCID 20362817 | — |
| Catalyst | Iron | HCID 23925 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-[(Methoxymethyl)sulfanyl]benzene-1,2-diamine | HCID 20362832 | — |
Reaction Steps
1.3 G. of 1-amino-2-nitro-4-methoxymethylthiobenzene is treated in 80 ml. methanol and 20 ml. water at reflux under nitrogen, with 0.7 g. ferrous sulfate and 2.8 g. iron (added in two portions) for four hours. The mixture is filtered, stripped under vacuum, and the residue recrystallized from cyclohexane. 1,2-Diamino-4-methoxymethylthiobenzene is thus obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04080461 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-ccf425ad4bf14da8acbee273d65e661c |
| Source note | uspto-grants-1978_03 |