HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → Azide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Sodium Nitrite | HCID 23668193 | — |
| Reactant | 1,2,4-Triazine-3,5-dione-6-carboxylic acid hydrazide hydrazine salt | HCID 131711058 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Azide | HCID 33558 | — |
| Product | 3,5-Dioxo-2,3,4,5-tetrahydro-1,2,4-triazine-6-carboxylic acid | HCID 5073653 | — |
Reaction Steps
A solution of 1.01 g. (0.005 mole) of 1,2,4-triazine-3,5-dione-6-carboxylic acid hydrazide hydrazine salt in 50 ml. of water, 20 ml. of 1N hydrochloric acid and 70 ml. of N,N-dimethylformamide was cooled to -3° C. A solution of 0.83 g. (0.012 mole) of sodium nitrite in 4 ml. of water was added to the hydrazide solution and the mixture was stirred at -3° C. to -5° C. for 30 minutes to give in solution the acid azide of 1,2,4-triazine-3,5-dione-6-carboxylic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04081441 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-3eb79b8e1a574c8a8ef528de851660b1 |
| Source note | uspto-grants-1978_03 |