HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → HCID 54233952, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 2,6,6-trimethylbicyclo[3.1.1]heptane-3-carboxylic acid | HCID 535109 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 54233952 | HCID 54233952 | — |
Reaction Steps
15 g of (+)-3-carboxypinane of optical rotation [α]D25 = +20.2° (c = 1, CH3OH) are boiled with excess thionyl chloride under reflux in the absence of moisture, until the evolution of gas has ceased. The excess thionylchloride is then distilled, followed by the acid chloride boiling at from 62° to 64° C/0.08 mm Hg and having an optical rotation of [α]D24 = +28.1° (pure).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04081477 |
| Source dataset | uspto-grants-1978_03 |
| ORD ID | ord-3dedf7450e5741488301ba1d57abe660 |
| Source note | uspto-grants-1978_03 |