Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tetrahydrofuran → 2-(p-Biphenylyl)-2-penten-4-ol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 반응물 | Sodium aluminum diethyl dihydride | HCID 16687524 | — |
| 반응물 | 2-(p-Biphenylyl)-2-penten-4-one | HCID 54565234 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 2-(p-Biphenylyl)-2-penten-4-ol | HCID 70545419 | — |
반응 단계
To a solution of 1.6 g. 2(p-biphenylyl)-2-penten-4-one in 25 ml. of dry tetrahydrofuran, at 0° C., 10 ml. of a solution of 25% (W/W) of sodium aluminum diethyl dihydride in toluene is dropwise added. After 20 minutes at 0° C., the mixture is poured onto ice and extracted with chloroform. Evaporation of the chloroform gives 2-(p-biphenylyl)-2-penten-4-ol, m.p. 137° - 138° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04081476 |
| 출처 데이터셋 | uspto-grants-1978_03 |
| ORD ID | ord-e18bc71998564db181d38f56bd67014a |
| 출처 메모 | uspto-grants-1978_03 |