4-Methylpyridine → HCID 70565168, compound

HRID 1679813Notes

Reaction equation

HRID 1679813 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1C.[S:8]([O-:12])([O-:11])(=[O:10])=[O:9].[OH:13][CH:14]([CH2:23][OH:24])[CH2:15][N+]1C=CC=CC=1C.[OH:25][CH:26]([CH2:35][OH:36])[CH2:27][N+]1C=CC=CC=1C.N1C=CC(C)=CC=1.S([O-])([O-])(=O)=O.OC(CO)C[N+]1C=CC(C)=CC=1.OC(CO)C[N+]1C=CC(C)=CC=1>>[S:8]([O-:12])([O-:11])(=[O:10])=[O:9].[OH:13][CH:14]([CH2:23][OH:24])[CH2:15][N+:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1.[OH:25][CH:26]([CH2:35][OH:36])[CH2:27][N+:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

5

Reactant 4

HCID 79634-MethylpyridineHCID 79752-MethylpyridineHCID 70568216HCID 70568216, compoundHCID 70568678HCID 70568678, compound

Product 1

HCID 70565168HCID 70565168, compound

Procedure

In analogy to the above-described procedure, α-picoline was used as a starting material to prepare bis-N-(2,3-dihydroxypropyl)-α-picolinium sulfate, which has the formula ##STR5## This compound was found to have a refractive index of nD20 =1.5268. Similarly, γ-picoline was used as a starting material to prepare bis-N-(2,3-dihydroxypropyl)-γ-picolinium sulfate, which has the formula ##STR6## and which had a refractive index of nD20 =1.5272.

Sources & evidence

ORD record
ord-d8698318c60942aca1153bb0849fe8e3
Source dataset
uspto-grants-1981_06
Patent number
US04270987

Reaction notes

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